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coal back to the mines, will sustain larger lines of transportation than have ever yet been employed in conveying to their markets the most important products of the country. The importation of foreign iron-already falling off in proportion to the increased consumption-must, before many years, cease, and be succeeded by exports for the supplies of other nations less bountifully provided for in this respect than the United States and Great Britain.

CHAPTER II.

COPPER.

THE early attempts to work copper mines in the United States have already been alluded to in the introductory remarks to the department of this work relating to mining industry. The ores of this metal are widely distributed throughout the country, and in almost every one of the states have been found in quantities that encouraged their exploration in the great majority of cases to the loss of those interested. The metal is met with in all the New England states, but only those localities need be named which have at times been looked upon as important. Copper occurs in a native or metallic state, and also in a variety of ores, or combinations of the metal with other substances. In these forms the metallic appearance is lost, and the metal is obtained by different metallurgical operations, an account of some of which will be presented in the course of this chapter. Until the discovery of the Lake Superior mines, native copper, from its scarcity, was regarded rather as a curiosity than as an important source of supply. The workable ores were chiefly pyritous copper, vitreous copper, variegated copper, the red oxide, the green carbonate or malachite, and chrysocolla. The first named, though containing the least proportion of copper, has furnished more of the metal than all the other ores together, and is the chief dependence of most of the mines. It is a double sulphuret of copper and iron, of bright yellow color, and consists, when pure, of about 34 per cent. of copper, 35 of sulphur, and 30 of iron. But the ore is always intermixed with quartz or other earthy minerals, by which its richness is greatly reduced. As brought out from the mine it may not contain more than 1 per cent. of copper, and when freed as far as practicable from foreign

substances by the mechanical processes of assorting, crushing, washing, jigging, etc., and brought up to a percentage of 6 or 7 of copper, it is in Cornwall a merchantable ore, and the mine producing in large quantity the poor material from which it is obtained may be a profitable one. Vitreous copper, known also as copper glance, and sulphuret of copper, is a lead gray ore, very soft, and contains 79.8 per cent. of copper, united with 20.2 per cent. of sulphur. It is not often found in large quantity. Variegated or purple copper is distinguished by its various shades of color and brittle texture. It yields, when pure, from 56 to 63 per cent. of copper, 21 to 28 of sulphur, and 7 to 14 of iron. The red oxide is a beautiful ore of ruby red color, and consists of 88.8 per cent. of copper and 11.2 per cent. of oxygen. It is rarely found in sufficient quantity to add much to the products of the mines. Green malachite is a highly ornamental stone, of richly variegated shades of green, famous as the material of costly vases, tables, etc., manufactured in Siberia for the Russian government. It is always met with in copper mines, especially near the surface, but rarely in large or handsome masses. It consists of copper 57.5, oxygen 14.4, carbonic acid 19.9, and water 8.2 per cent. Chrysocolla is a combination of oxide of copper and silica, of greenish shades, and is met with as an incrustation upon other copper ores. It often closely resembles the malachite in appearance. It contains about 36 per cent. of copper.

The first mines worked in the United States were peculiar for the rich character of their ores. These were, in great part, vitreous and variegated copper, with some malachite, and were found in beds, strings, and bunches in the red sandstone formation, especially along its line of contact with the gneiss and granitic rocks in Connecticut, and with the trap rocks in New Jersey. The mine at Simsbury, in Connecticut, furnished a considerable amount of such ores from the year 1709 till it was purchased, about the middle of the last century, by the state, from which time it was occupied for sixty years as a prison, and worked by the convicts; not, however, to much profit. 1830 it came into possession of a company, but was only worked for a short time afterward. On the same geological range, but lying chiefly in the gneiss rocks, the most productive of these mines was opened in

In

sales of copper ores during the three years the mines were actively worked amounted to over $40,500; but the product was not sufficient to meet the expenditures.

1836, in Bristol, Conn. It was vigorously-extensive mining operations have been worked from 1847 to 1857, and produced carried on; a shaft upon the latter having larger amounts of rich vitreous and pyritous reached in 1853 the depth of 396 feet. The ores than have been obtained from any other mine in the United States. No expense was spared in prosecuting the mining, and in furnishing efficient machinery for dressing the ores. Although 1800 tons of ore, producing over $200,000, were sent to market, the ore yielding from 18 to 50 per cent. of copper, the mine proved a losing affair, and was finally abandoned in 1857.

The mines in Frederick county, Maryland, in the neighborhood of Liberty, were near the red sandstone formation, though included in argillaceous and talcose slates. A number of them have been worked at different times up to the year 1853, when they were finally given up as unprofitable.

and the mine was reported as improving. The ore sent to the smelting works at Baltimore, in December of that year, yielded 16.03 per cent. of copper. Within seven miles of Baltimore the Bare Hill mine has produced considerable copper, associated with the chromic iron of that region.

The New Jersey mines have all failed. from insufficient supply of the ores. The Schuyler mine, at Belleville, produced rich A more newly discovered and richer copvitreous copper and chrysocolla, disseminated per district in Maryland is near Sykesville, through a stratum of light brown sandstone, on the Baltimore and Ohio railroad, 32 miles of 20 to 30 feet in thickness, and dipping at from Baltimore, in a region of micaceous, an angle of 12°. During the periods of its talcose, and chloritic slates. A large bed of being worked in the last century, the exca- specular iron ore lying between the slates vations reached the depth of 200 feet, and was found to contain, at some depth below were carried to great distances on the course the surface, carbonates and silicates of copof the metalliferous stratum. The mine was per, and still further down copper pyrites. then so highly valued that an offer of £500,- In the twelve months preceding April 1, 000, made for it by an English company, was 1857, 300 tons had been mined and sent to refused by the proprietor, Mr. Schuyler. In market, the value of which was $17,896.92, 1857-58 attempts were made by a New York company to work the mine again, but the enterprise soon failed. Among the other mines which have been worked to considerable extent in New Jersey are the Flemington mine, which resembled in the character of its ore the Schuyler mine, and the Bridgewater mine, near Somerville, at which Like the last two named, all the other lonative copper in some quantity was found in calities of copper ores of any importance the last century; two pieces met with in 1754 along the Appalachian chain and east of it weighing together, it was reported, 1,900 lbs. are remote from the range of the red sandA mine near New Brunswick also furnished stone, and belong to older rock formations. many lumps of native copper, and thin sheets In the granites of New Hampshire, pyritous of the metal were found included in the sand- copper has been found in many places, but has stone. At different times this mine has been nowhere been mined to any extent. In Verthoroughly explored, to the loss of those en-mont, mining operations were carried on for gaged in the enterprise. In Somerset county, several years upon a large lode of pyritous the Franklin mine, near Griggstown, has been copper, which was traced several miles worked to the depth of 100 feet. Carbonate through Vershire and Corinth. At Strafand red oxide of copper were found in the ford, pyritous ores were worked in 1829 and shales near the trap, but not in quantity suf- afterward, both for copperas and copper. In ficient to pay expenses. In Pennsylvania, New York, excellent pyritous ores were pronear the Schuylkill river, in Montgomery and duced at the Ulster lead mine in 1853. Chester counties, many mines have been Among other sales of similar qualities of ore, worked for copper and lead at the junction one lot of 50 tons produced 24.3 per cent. of of the red sandstone and gneiss. Those veins included wholly in the shales of the red sandstone group were found to produce copper chiefly, while those in the gneiss were productive in lead ores. At the Perkiomen and Ecton mines-both upon the same lode

copper.

In Virginia, rich ores of red oxide of copper, associated with native copper and pyritous copper, are found in the metamorphic slates at Manasses Gap, and also in many other places further south along the Blue

Ridge. The very promising appearance of the ores, and their numerous localities, would encourage one to believe that this will prove to be a copper region, were it not that, when explored, the ores do not seem to lie in any regular form of vein. In the southern part of the state, in Carroll, Floyd, and Grayson counties, copper was discovered in 1852, and mines were soon after opened in a district of metamorphic slates, near their junction with the lower silurian limestones. The copper was met with in the form of pyritous ore, red oxide, and black copper, beneath large outcropping masses of hematite iron ore, or gossan. Some of the shipments are said to have yielded over 20 per cent. of copper. The amount of ores sent cast, over the Virginia and Tennessee railroad, in 1855, was 1,931,403 lbs.; in 1856, 1,972,834 lbs.; and in the nine months ending June 30, 1857, 1,085,997 lbs.; 1858, 688,418 lbs.; 1859, 1,151,132 lbs.; and 1860, 2,679,673 lbs. Copper ores are very generally met with in the gold mines of this state, and further south, but the only one of them that has been worked expressly for copper is that of the North Carolina Copper Company, in Guilford county. From this a considerable amount of pyritous copper ores were sent to the north in 1852 and 1853.

In Tennessee, an important copper region lies along the southern line of Polk county, and extends into Gilmer county, Georgia. The ore was first found in 1847, associated with masses of hematite iron ores, which formed great outcropping ledges, traceable for miles from south-west to north-cast along the range of the micaceous and talcose slates. An examination of the ores, made to ascertain the cause of their working badly in the furnace, was the means of corroborating or giving importance to the discovery of the copper. In 1851 copper mining was commenced, and afterward prosecuted with great activity by a number of companies. The ore was found in seven or eight parallel lodes of the ferruginous matters, all within a belt. of a mile in width. At the surface there was no appearance of it, but as the explorations reached the depth of seventy-five or one hundred feet below the surface of the hills, it was met with in various forms, resulting from the decomposition of pyritous copper, and much mixed with the ochreous matters derived from a similar source. In a soft black mass, easily worked by the pick, and of extraordinary dimensions, were found

intermixed different oxides and other ores of copper, yielding various proportions of metal, and much of it producing 20 per cent. and more, fit to be barrelled up at once for transportation. This ore spread out in a sheet, varying in width at the different mines; at the Eureka mine it was 50 feet wide, and at the Hiwassee 45 feet, while at the Isabella mine the excavations have been extended between two walls 250 feet apart. In depth this ore is limited to a few feet only, except as it forms bunches running up into the gossan or ochreous ores. Below the black ore is the undecomposed lode, consisting of quartz, more or less charged with pyritous copper, red oxide, green carbonate, and gray sulphuret of copper; and it is upon these the permanent success of the mines must depend. About 14 mining companies have been engaged in this district, and the production of the most successful of them was as follows, up to the year 1858: Isabella, 2,500 tons; Calloway, 200; Mary's, 1,500; Polk county, 2,100; Tennessee, 2,200; Hiwassee, 2,500; Hancock, 2,000— making a total of 13,000 tons, yielding from 15 to 40 per cent. of copper, and worth $100 per ton, or $1,300,000. In addition to this, the products of the London mine, yielding an average of 45 per cent. of copper, amounted to over $200,000 in value; and the products of the Eureka mine were rated for 1855 at $86,000; for 1856 at $123,000; and for 1857 at $136,000. The value of the ores remaining at the mines too poor to transport, but valuable to smelt in furnaces on the spot, was estimated at $200,000 more. Furnaces for smelting, on the German plan, were in operation in 1857, and produced the next year 850 tons of matt, or regulus. At the Eureka mine, in 1858, there were 4 reverberatory furnaces, 2 blast, and 2 calcining furnaces. The fuel employed is wood and charcoal. By the introduction of smelting operations, ores of 5 to 6 per cent. are now advantageously reduced.

In 1857 the mines of a large portion of this district were incorporated into the socalled Union Consolidated Mining Company, and most of the other mines were taken up by the Burra Burra Company and the Polk County Company. The principal interests in the last two are held in New Orleans. The first named own 11 mines, of which they are working three only, with a monthly production of 750 to 800 tons of 12 per cent. copper, besides 5 or 6 tons of precipitate

copper. This is metallic copper, precipitated from the waters of the mine by means of scrap iron thrown into the vats in which these waters are collected. The iron being taken up by the acids which hold the copper in solution, the latter is set free, and deposited in fine metallic powder. The ore is smelted in furnaces constructed on the German plan, and being put through twice, produce a regulus of 55 per cent. As soon as the proper furnaces and refineries can be constructed, it is intended to make ingot copper, and by working more of the mines belonging to the company it is expected the monthly production will soon be raised to 2,000 tons of 10 to 12 per cent. ore.

crease in the supply of the metal will be derived from this source.

The existence of native copper on the shores of Lake Superior, is noticed in the reports of the Jesuit missionaries of 1659 and 1666. Pieces of the metal 10 to 20 lbs. in weight were seen, which it is said the Indians reverenced as sacred; similar reports were brought by Father Dablou in 1670, and by Charlevoix in 1744. An attempt was made in 1771 by an Englishman, named Alexander Henry, to open a mine near the forks of the Ontonagon, on the bank of the river, where a large mass of the metal lay exposed. He had visited the region in 1763, and returned with a party prepared for more The two other companies have erected ex- thoroughly exploring its resources. They, tensive smelting works; and the mines of however, found no more copper besides the the Burra Burra are producing 450 to 500 loose mass, which they were unable to retons per month of 14 per cent. ore, and move. They then went over to the north those of the Polk County Company about shore of the lake, but met with no better 300 tons of 15 per cent. ore. Both com- success there. General Cass and Mr. H. R. panies will soon be able to make ingot cop- Schoolcraft visited the region in 1819, and per. The report of the Union Consolidated reported on the great mass upon the OntonCompany for the first year of their opera- agon. Major Long, also, in 1823, bore wittions presents, against expenditures amount-ness to the occurrence of the metal along ing to $307,182.77, receipts of $457,803.73, the shores of the lake. The country, till leaving a profit of $150,620.96. A large the ratification of the treaty with the Chipportion of the regulus is shipped to England for sale.

The profits of these mines were greatly reduced the first few years of their operation by the necessity of transporting the ores 40 miles to a railroad, and thence more than 1,000 miles by land and water to the northern smelting works. The establishment of furnaces at the mines not only reduces this source of loss, but renders the great body of poorer ores available, which they were not before. A railroad is now in process of construction to connect the mines with the Georgia railroads.

pewa Indians in 1842, was scarcely ever visited except by hunters and fur-traders, and was only accessible by a tedious voyage in canoes from Mackinaw. The fur companies discouraged, and could exclude from the territory, all explorers not going there under their auspices. Dr. Douglass Houghton, the state geologist of Michigan, in the territory of which these Indian lands were included, made the first scientific examination of the country in 1841, and his reports first drew public attention to its great resources in copper. His explorations were continued both under the state and general government until they were suddenly terminated with his life by the unfortunate swamping of his boat in the lake, near Eagle river, October 13, 1845.

West of the Alleghanies, the only copper mines, besides those of Lake Superior, are in the lead region of Wisconsin, Iowa, and Missouri. A considerable number of them have been worked to limited extent, and In 1844 adventurers from the eastern states small blast furnaces have been in operation began to pour into the country, and mining smelting the ores. These were found only operations were commenced at various places near the surface, in the crevices that con- near the shore, on Keweenaw Point. The tained the lead ores; and in Missouri, in companies took possession under permits horizontal beds in the limestone, along the from the general land office, in anticipation line of contact of the granite. The ores of the regular surveys, when the tracts could were mixed pyritous copper and carbonate, be properly designated for sale. Nearly always in very limited quantity. The amount one thousand tracts, of one mile square each, of copper produced has been unimportant, were selected the greater part of them at and it is not likely that any considerable in- | random, and afterward explored and aban

doned. In 1846 a geological survey of the region was authorized by Congress, which was commenced under Dr. C. T. Jackson, and completed by Messrs. Foster and Whitney in 1850. At this time many mines were in full operation, and titles to them had been acquired at the government sales.

The

and nowhere in quantities to justify the continuation of mining operations that were commenced upon them. The veins on Keweenaw Point cross the ridges nearly at right angles, penetrating almost vertically through the trap and the sandstones. Their productiveness is, for the most part, limited to certain amygdaloidal belts of the trap, which alternate with other unproductive beds of gray compact trap, and the mining explorations follow the former down their slope of 40°, more or less, toward the north. thickness of the veins is very variable, and also their richness, even in the amygdaloid. The copper is found interspersed in pieces of all sizes through the quartz vein stones and among the calcareous spar, laumonite, prehnite, and other minerals associated with the quartz. These being extracted, piles are made of the poorer sorts, in which the metal is not sufficiently clear of stone for shipment, and these are roasted by firing the wood in termixed through the heaps. By this proc

is more readily broken and removed. The lumps that will go into barrels are called "barrel work," and are packed in this way for shipment. Larger ones, called "masses," some of which are huge, irregular-shaped blocks of clean copper, are cut into pieces that can be conveniently transported, as of one to three tons weight each. This is done by means of a long chisel with a bit threefourths of an inch wide, which is held by one man and struck in turns by two others with a hammer weighing 7 or 8 lbs. A groove is thus cut across the narrowest part of the mass, turning out long chips of copper onefourth of an inch thick, and with each suc

The copper region, as indicated by Dr. Houghton, was found to be nearly limited to the range of trap hills, which are traced from the termination of Keweenaw Point toward the south-west in a belt of not more than two miles in width, gradually receding from the lake shore. The upper portion of the hills is of trap rock, lying in beds which dip toward the lake, and pass in this direction under others of sandstone, the outcrop of which is along the northern flanks of the hills. Isle Royale, near the north shore of the lake, is made up of similar formations, which dip toward the south. These rocks thus appear to form the basin in which the portion of Lake Superior lying between is held. The trap hills are traced from Kewee-ess the stone entangled among the copper naw Point in two or three parallel ridges of 500 to 1,000 feet elevation, crossing Portage lake not far from the shore of Lake Superior, and the Ontonagon river about 13 miles from its mouth. They thence reach further back into the country beyond Agogebic lake, full 120 miles from the north-eastern termination. Another group of trap hills, known as the Porcupine mountains, comes out to the lake shore some 20 miles above the mouth of the Ontonagon, and this also contains veins of copper, which have been little developed until the explorations commenced near Carp lake in these mountains in 1859. These have resulted in a shipment of over 20 tons of rough copper in 1860, and give en-ceeding cut the groove is deepened to the couragement to this proving a copper-pro- same extent until it reaches through the mass. ducing district. The formations upon Isle The process is slow and tedious, a single cut Royale, which is within the boundary of the sometimes occupying the continual labor of United States, although they are similar to three men for as many weeks, or even longthose of the south shore, and contain copper er. This work is done in great part beveins upon which explorations were vigor- fore the masses can be got out of the ously prosecuted, have not proved of impor- mine. The masses are found in working the tance, and no mines are now worked there. vein, often occupying the whole space beThe productive mines are comprised in three tween the walls of trap rock, standing updistricts along the main range of the trap on their edges, and shut in as solidly as if hills. The first is on Keweenaw Point, the all were one material. To remove one of the second about Portage lake, and the third very large masses is a work of many months. near the Ontonagon river. All the veins It is first laid bare along one side by extendare remarkable for producing native copper alone, the only ores of the metal being chiefly of vitreous copper found in a range of hills on the south side of Keweenaw Point,

ing the level or drift of the mine through the trap rock. The excavation is carried high enough to expose its upper edge and down to its lower line; but on account of ir

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